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dc.contributor.authorDeshmukh, Madhukar B-
dc.contributor.authorJadhav, Sunil D-
dc.contributor.authorKadam, Shashikant V-
dc.date.accessioned2008-04-01T11:12:09Z-
dc.date.available2008-04-01T11:12:09Z-
dc.date.issued2007-06-
dc.identifier.issn0376-4699-
dc.identifier.urihttp://hdl.handle.net/123456789/641-
dc.description989-994en_US
dc.description.abstractA mild method for the copper-catalyzed substitution of aldehyde acylals with organomanganese reagents is reported. This operationally simple C-C bond-forming protocol uses different Cu(I) catalysts. Acylal from trans-cinnamaldehyde furnishes conjugated addition product when reacted with alkyl and aryl organomanganese reagents in presence of 10 mol % of Cu(NCMe)₂(PPh₃)₂[BF₄] and 2 equivalent of Me₃Si-Cl as an accelerator. This reagent can be efficiently used in the substitution of one acetate group of aromatic acylal to form esters in high yield.en_US
dc.language.isoen_USen_US
dc.publisherCSIRen_US
dc.sourceIJCB Vol.46B(6) [June 2007]en_US
dc.subjectSubstitutionen_US
dc.subjectAcylalsen_US
dc.subjectOrganomanganese reagentsen_US
dc.titleCopper-catalyzed substitution reactions of acylal with organomanganese reagentsen_US
dc.typeArticleen_US
Appears in Collections:IJC-B Vol.46B(06) [June 2007]

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