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|Title:||Synthesis of conformationally constrained ⍺-imino acid derivatives via ring-closing metathesis|
|Keywords:||Peptidomemitics;Conformationally constrained amino acids;Conformationally constrained imino acids;Ring-closing metathesis|
|Abstract:||Conformationally constrained amino acid derivatives are useful in the synthesis of peptidomimetics. Seven-, and eight-membered conformationally constrained ⍺-imino acid derivatives have been prepared via RCM (ring-closing metathesis). Interestingly, attempts to achieve the synthesis of nine-membered imino acid derivative resulted in the formation of dimeric, 18-membered macrocyclic bis-⍺-imino acid derivative.|
|Appears in Collections:||IJC-B Vol.46B(06) [June 2007]|
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|IJCB 46B(6) (2007) 975-979.pdf||111.48 kB||Adobe PDF||View/Open|
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