NISCAIR Online Periodicals Repository

Research Journals >
Indian Journal of Chemistry -Section A (IJC-A) >
IJC-A Vol.47A [2008] >
IJC-A Vol.47A(03) [March 2008] >

Title: Synthesis, characterization and properties of some ternary copper(II) complexes containing NOS donor Schiff base and NN donor bidentate ligands
Authors: Patel, R N
Gundla, V L N
Patel, D K
Issue Date: Mar-2008
Publisher: CSIR
IPC CodeInt. Cl. ⁸ CO7F1/08; CO7C251/02
Abstract: Six ternary copper(II) complexes, viz., [Cu(SAT)(H₂O)] (1), [Cu(SAT)(phen)].0.5 H2O (2), [Cu(SAT)(bipy)] (3), [Cu(SAA)(dmp)] (4), [Cu(SAT)(en)] (5) and [Cu(SAT)(temed)] (6), where SAT = Salicylideneaminothiophenol, phen = 1,10-phenanthroline, bipy = 2,2-bipyridyl, dmp = 2,9-dimethyl 1,10-phenanthroline, en = ethylenediamine, temed = N,N,N',N'-tetramethylethylinediamine have been synthesized and characterized by various physico-chemical techniques. The metal ligand bonding parameters evaluated from the EPR spectra of the complexes indicate strong in-plane σ and in-plane π bonding. The magnetic and spectroscopic data indicate a square planar geometry for complex 1 and a square pyramidal geometry for remaining complexes. The crystal structure of complex 2 has been determined by X-ray diffraction technique. The superoxide dismutase activity of the complexes has also been measured and discussed.
Page(s): 353-360
ISSN: 0376-4710
Source:IJC-A Vol.47A(03) [March 2008]

Files in This Item:

File Description SizeFormat
IJCA 47A(3) (2008) 353-360.pdf273.74 kBAdobe PDFView/Open
 Current Page Visits: 943 
Recommend this item


Online Submission of Articles |  NISCAIR Website |  National Knowledge Resources Consortium |  Contact us |  Feedback

Disclaimer: NISCAIR assumes no responsibility for the statements and opinions advanced by contributors. The editorial staff in its work of examining papers received for publication is helped, in an honorary capacity, by many distinguished engineers and scientists.

CC License Except where otherwise noted, the Articles on this site are licensed under Creative Commons License: CC Attribution-Noncommercial-No Derivative Works 2.5 India

Copyright © 2015 The Council of Scientific and Industrial Research, New Delhi. All rights reserved.

Powered by DSpace Copyright © 2002-2007 MIT and Hewlett-Packard | Compliant to OAI-PMH V 2.0

Home Page Total Visits: 168932 since 01-Sep-2015  Last updated on 29-Jun-2016Webmaster: