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Title: A convenient stereoselective synthesis of <img src='/image/spc_char/beta.gif'>-D-glucopyranosides
Authors: Joshi, Vishal Y
Sawant, Manohar R
Keywords: Koenigs-Knorr method
<img src='/image/spc_char/beta.gif'>-D-glucopyranosides
alkyl glucosides
Issue Date: Feb-2006
Publisher: CSIR
Series/Report no.: <b>Int</b>.<b>Cl</b>.<b><sup>7</sup> C 07 H 3/00</b>
Abstract: The Koenigs-Knorr method plays a prominent role in the stereoselective synthesis of alkyl D-glucopyranosides <i style="">via</i> glycosidic linkage. Such an approach requires costly and toxic promoter salts of silver or mercury, which have additional separation problems. In a novel method a less toxic promoter salt like LiCO<sub>3 </sub>is used for glycosidation of several fatty alcohols including an aromatic alcohol. LiCO<sub>3</sub> can be easily separated from the reaction mass and gives good yield.
Description: 461-465
ISSN: 0975-0983(Online); 0376-4699(Print)
Appears in Collections:IJC-B Vol.45B(02) [February 2006]

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