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Title: A convenient stereoselective synthesis of -D-glucopyranosides
Authors: Joshi, Vishal Y
Sawant, Manohar R
Keywords: Koenigs-Knorr method;-D-glucopyranosides;alkyl glucosides;LiCO3
Issue Date: Feb-2006
Publisher: CSIR
IPC Code: Int.Cl.7 C 07 H 3/00
Abstract: The Koenigs-Knorr method plays a prominent role in the stereoselective synthesis of alkyl D-glucopyranosides via glycosidic linkage. Such an approach requires costly and toxic promoter salts of silver or mercury, which have additional separation problems. In a novel method a less toxic promoter salt like LiCO3 is used for glycosidation of several fatty alcohols including an aromatic alcohol. LiCO3 can be easily separated from the reaction mass and gives good yield.
Page(s): 461-465
ISSN: 0975-0983(Online); 0376-4699(Print)
Appears in Collections:IJC-B Vol.45B(02) [February 2006]

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