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dc.contributor.authorPeriasamy, Mariappan-
dc.contributor.authorAnwar, Shaik-
dc.contributor.authorReddy, Meda Narsi-
dc.description.abstractRacemic aminonaphthols are obtained in 70-95% yield by simple and straightforward condensation of benzaldehyde, 2-naphthol and 1° or 2° amines in ethanol solvent under refluxing conditions. The racemic aminonaphthols 1-(α-aminobenzyl)-2-naphthol and 1-(α-pyrrolidinylbenzyl)-2-naphthol have been resolved using l-(+)-tartaric acid. The racemic 1-(α-N-butylaminobenzyl)-2-naphthol and 1-(α-piperidylbenzyl)-2-naphthol have been resolved using R-(+)-BINOL and boric acid. The racemic (2-methoxynaphth-1-yl)benzylamine is resolved using dibenzoyl-l-(-)-tartaric acid. The readiliy accessible chiral aminonaphthols are useful for resolution of important moieties like racemic BINOL, ibuprofen and mandelic aciden_US
dc.sourceIJC-B Vol.48B(09) [September 2009]en_US
dc.subjectBetti reactionen_US
dc.subjectdiastereomeric complexesen_US
dc.subjectL-(+)-tartaric aciden_US
dc.subjectdibenzoyl-L-(-)-tartaric aciden_US
dc.subjectmandelic aciden_US
dc.titleSimple and convenient methods for synthesis, resolution and application of aminonaphtholsen_US
Appears in Collections:IJC-B Vol.48B(09) [September 2009]

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