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IJC-A Vol.47A(02) [February 2008] >


Title: Syntheses, spectroscopic studies, crystal structure and complexation reactions of N- (2 or 4-hydroxylphenyl) benzaldimine
Authors: De, Rajib Lal
Mandal, Mahuya
Roy, Lovely
Mukherjee, Jaydeep
Issue Date: Feb-2008
Publisher: CSIR
IPC CodeInt. Cl. ⁸ C07F1/08; C07F3/06; C07F15/04; C07F15/06
Abstract: Two monobasic bidentate Schiff base ligands (SBH) derived from the condensation reaction between benzaldehyde and 2-aminophenol (BENOPH) or 4-aminophenol (BENPAPH) have been subjected to complexation reactions stabilising the bis-ligated complexes MII(SB)₂ (MII=Cu, Ni, Co and Zn) where aminophenolic (-OH) groups participate in the complexation reaction. The newly synthesized Schiff bases and their complexes are characterized by elemental analysis, magnetic, spectroscopic and electrochemical studies. Crystal structure studies performed on BENPAPH show it to crystallize in the monoclinic form, space group P2₁/c; Z=4 with a, 6.500(7); b, 14.885(3); c, 10.852(2) Å and β, 91.489(12)º.
Page(s): 207-213
ISSN: 0376-4710
Source:IJC-A Vol.47A(02) [February 2008]

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