Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/58199
Title: Study of solid state structural and bonding features of (E)-1-(4-bromophenyl)-3-(1-H-indol-3-yl)-prop-2-en-1-one
Authors: Banpurkar, Anita R
Wazalwar, Sachin S
Perdih, Franc
Keywords: Indolyl chalcone;indole-3-carbaldehyde;4-bromoacetophenone;microwave assisted;X-ray diffraction;cyclic tetramer
Issue Date: Sep-2021
Publisher: NIScPR-CSIR, India
Abstract: Single-crystal study of indolyl chalcone (E)-1-(4-bromophenyl)-3-(1-H-indol-3-yl)-prop-2-en-1-one is reported here. It has been synthesized by microwave assisted method from indole-3-carbaldehyde and 4-bromo acetophenone by Claisen-Schmidt reaction. IR,1H NMR and HRMS data is reported here. The crystalline structure of this compound is described within the sp. gr. I -4; its unit cell parameters are a = 23.9636(17)Å,b = 23.9636(17)Å,c = 5.1428(5)Å. Crystallographic study shows formation of hydrogen-bonded cyclic tetramer around a 2-fold axis and 4-fold roto-inversion axis through N1–H1···O1 interactions between the indolic NH group as a hydrogen-bond donor and the carbonyl O atom as a hydrogen-bond acceptor.
Page(s): 1211-1214
URI: http://nopr.niscair.res.in/handle/123456789/58199
ISSN: 0975-0983(Online); 0376-4699(Print)
Appears in Collections:IJC-B Vol.60B(09) [September 2021]

Files in This Item:
File Description SizeFormat 
IJC (Section B), 60B, 1211-1214 (Sep,2021).pdfMain Article717.88 kBAdobe PDFView/Open
IJC (Section B), 60B, 1211-1214 (Sep,2021) Suppl. Data.pdfSupplementary Data598.12 kBAdobe PDFView/Open


Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.