Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/5812
Title: Syntheses, crystal structures and antibacterial activities of two end-on azido-bridged copper(II) complexes with Schiff bases
Authors: Hui, Rui-Hua
Zhou, Peng
You, Zhong-Lu
Keywords: Coordination chemistry
Schiff base
Copper
Dinuclear complexes
X-ray crystallography
Issue Date: Aug-2009
Publisher: CSIR
Series/Report no.: Int. Cl.<sup>9</sup> C07C251/02; C07F1/08
Abstract: Reactions of 4-bromo-2-[(2-diethylaminoethylimino)methyl] phenol and 1-[(2-ethylaminoethylimino)methyl]-naphthalen-2-ol with copper acetate and ammonium thiocyanate, respectively, afford two centrosymmetric azido-bridged dinuclear copper complexes, [Cu(L1)<sub>2</sub>(μ<sub>1,1</sub>-N<sub>3</sub>)<sub>2</sub>] (<b style="">1</b>) and [Cu(L2)<sub>2</sub>(μ<sub>1,1</sub>-N<sub>3</sub>)<sub>2</sub>] (<b style="">2</b>). Each Cu atom in the complexes is five-coordinate in a distorted square-pyramidal geometry. The antibacterial activities of the Schiff base and the two complexes have been tested. <b style=""></b>
Description: 1102-1106
URI: http://hdl.handle.net/123456789/5812
ISSN: 0975-0975 (Online); 0376-4710 (Print)
Appears in Collections:IJC-A Vol.48A(08) [August 2009]

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