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IJC-A Vol.48A(08) [August 2009] >


Title: Syntheses, crystal structures and antibacterial activities of two end-on azido-bridged copper(II) complexes with Schiff bases
Authors: Hui, Rui-Hua
Zhou, Peng
You, Zhong-Lu
Keywords: Coordination chemistry
Schiff base
Copper
Dinuclear complexes
X-ray crystallography
Issue Date: Aug-2009
Publisher: CSIR
IPC CodeInt. Cl.9 C07C251/02; C07F1/08
Abstract: Reactions of 4-bromo-2-[(2-diethylaminoethylimino)methyl] phenol and 1-[(2-ethylaminoethylimino)methyl]-naphthalen-2-ol with copper acetate and ammonium thiocyanate, respectively, afford two centrosymmetric azido-bridged dinuclear copper complexes, [Cu(L1)21,1-N3)2] (1) and [Cu(L2)21,1-N3)2] (2). Each Cu atom in the complexes is five-coordinate in a distorted square-pyramidal geometry. The antibacterial activities of the Schiff base and the two complexes have been tested.
Page(s): 1102-1106
ISSN: 0975-0975 (Online); 0376-4710 (Print)
Source:IJC-A Vol.48A(08) [August 2009]

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