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Indian Journal of Chemistry -Section A (IJC-A) >
IJC-A Vol.48A [2009] >
IJC-A Vol.48A(08) [August 2009] >
| Title: | Syntheses, crystal structures and antibacterial activities of two end-on azido-bridged copper(II) complexes with Schiff bases |
| Authors: | Hui, Rui-Hua
Zhou, Peng
You, Zhong-Lu |
| Keywords: | Coordination chemistry
Schiff base
Copper
Dinuclear complexes
X-ray crystallography |
| Issue Date: | Aug-2009 |
| Publisher: | CSIR |
| IPC Code: | Int. Cl.9 C07C251/02; C07F1/08 |
| Abstract: | Reactions of 4-bromo-2-[(2-diethylaminoethylimino)methyl] phenol and 1-[(2-ethylaminoethylimino)methyl]-naphthalen-2-ol with copper acetate and ammonium thiocyanate, respectively, afford two centrosymmetric azido-bridged dinuclear copper complexes, [Cu(L1)2(μ1,1-N3)2] (1) and [Cu(L2)2(μ1,1-N3)2] (2). Each Cu atom in the complexes is five-coordinate in a distorted square-pyramidal geometry. The antibacterial activities of the Schiff base and the two complexes have been tested. |
| Page(s): | 1102-1106 |
| ISSN: | 0975-0975 (Online); 0376-4710 (Print) |
| Source: | IJC-A Vol.48A(08) [August 2009]
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