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Title: Rational design and expeditious synthesis of aromatic cyanodienone derivatives assisted by cyanide-halide exchange
Authors: Zeraatpisheh, Fatemeh
Abadast, Fatemeh
Shahmorad, Maryam
Keywords: Cyanodienone,;triarylpyrylium perchlorate;1-n-butyl-3-methylimidazolium cyanide;1-n-butyl-3-methylimidazolium cyanide;environment friendly methodology;ionic liquid
Issue Date: Jun-2021
Publisher: NIScPR-CSIR, India
Abstract: 1-n-Butyl-3-methylimidazolium cyanide ([bmim]CN), in the presence of [bmim]Br has been prepared and used for the first time as the medium as well as reagent for the synthesis of aromatic cyanodienones from the corresponding triarylpyrylium perchlorates by cyanide-halide exchange. The [bmim]CN having a reactive anion, accelerated reaction technique without external solvent renders the whole synthesis into a truly ecofriendly protocol. The products is isolated without aqueous work-up in high purity and excellent yield.
Page(s): 845-848
ISSN: 0975-0983(Online); 0376-4699(Print)
Appears in Collections:IJC-B Vol.60B(06) [June 2021]

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