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Title: Efficient and region-selective conversion of octanes to epoxides under ambient conditions: Performance of tri-copper catalyst, [Cu3I(L)]+1 (L=7-N-Etppz)
Authors: Nagababu, Penumaka
Paul, Perala Sudheer
Reddy, Thatiparthi Byragi
Krupadam, Reddithota J
Keywords: Epoxidation;Region-selectivity;Ambient conditions;Tri-copper catalyst
Issue Date: May-2021
Publisher: NISCAIR-CSIR, India
Abstract: In this paper, is described the conversion of the octane group of hydrocarbons into industrially important epoxides using tri-copper catalyst, [Cu3I(L)]+1 (L=7-N-Etppz). The role of hydrogen peroxide as a sacrificial oxygen donor during catalytic conversion to epoxides has been investigated. The performance of the catalyst has been evaluated in terms of turnover numbers (TON) and turnover frequencies (TOF) reported in this article.
Page(s): 742-745
ISSN: 0975-0983(Online); 0376-4699(Print)
Appears in Collections:IJC-B Vol.60B(05) [May 2021]

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