Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/57491
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dc.contributor.authorAshwini-
dc.contributor.authorBhat, Gopalakrishna N-
dc.contributor.authorNazareth, Ronald A-
dc.date.accessioned2021-06-15T09:12:29Z-
dc.date.available2021-06-15T09:12:29Z-
dc.date.issued2021-05-
dc.identifier.issn0975-0975(Online); 0376-4710(Print)-
dc.identifier.urihttp://nopr.niscair.res.in/handle/123456789/57491-
dc.description649-655en_US
dc.description.abstractA novel Schiff base 4-{(E)-[(3-methyl-5-sulphanyl-4H-1,2,4-triazol-4-yl)imino]methyl}benzaldehyde (MSTB) and its complexes with Ag(I), Hg(II), Cu(II), Ni(II) and Co(II) have been prepared. MSTB is prepared by the condensation reaction between triazole and terephthaldehyde. In complexes, MSTB molecules are found to link with the metal ion, through thiolsulphur after deprotonation and the nitrogen of the azomethine group. The composition of the complexes are found to be ML where M =Ag, ML2 where M=Zn, Hg and ML2(H2O)2 where M= Co, Ni. Linear polymeric structure is proposed for Ag(I) complex, tetrahedral structure is proposed for Zn(II) and Hg(II) complexes and octahedral structure is proposed for Co(II) and Ni(II) complexes.en_US
dc.language.isoen_USen_US
dc.publisherNISCAIR-CSIR, Indiaen_US
dc.rights CC Attribution-Noncommercial-No Derivative Works 2.5 Indiaen_US
dc.sourceIJC-A Vol.60A(05) [May 2021]en_US
dc.subjectMSTBen_US
dc.subjectAg(I)en_US
dc.subjectHg(II)en_US
dc.subjectCu(II)en_US
dc.subjectNi(II)en_US
dc.subjectCo(II) complexen_US
dc.subjectML2(H2O)2en_US
dc.subjectTerephthaldehydeen_US
dc.titleSynthesis of 4-{(E)-[(3-methyl-5-sulphanyl-4H-1,2,4-triazol-4-yl)imino]methyl} benzaldehyde and its complexes with Ag(I), Hg(II), Zn(II), Co(II), Ni(II) ions and its characterisationen_US
dc.typeArticleen_US
Appears in Collections:IJC-A Vol.60A(05) [May 2021]

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