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dc.contributor.authorJin, Hongzhe-
dc.contributor.authorPeng, Xiaoming-
dc.contributor.authorGuan, Lei-
dc.contributor.authorWang, Ying-
dc.contributor.authorXiong, Xuejia-
dc.identifier.issn0975-0975(Online); 0376-4710(Print)-
dc.description.abstractA new yttrium complex, [Y2(H2Dhbds)3(phen)2]·[Y2(H2Dhbds)2(H2Thbs)(phen)2] (1) (Na2H2Dhbds = 4,5-dihydroxy-1,3-benzenedisulfonic acid disodium salt; NaH3Thbs = 2,3,5-trihydroxy-1-benzenesulfonic acid sodium salt), has been synthesized and structurally characterized. Complex 1 consists of two dinuclear structural units bridged by H2Dhbds2- and H2Thbs2- ligands, where phen molecules act as N, N-bidentate ligands, chelating Y atoms. The dinuclear structural units are connected by π-π stacking interactions between phen molecules, generating a one-dimensional chain structure. In addition, complex 1 exhibits the broad fluorescent emission band at 365 nm, which originates from intraligand charge transitions.en_US
dc.publisherNISCAIR-CSIR, Indiaen_US
dc.rights CC Attribution-Noncommercial-No Derivative Works 2.5 Indiaen_US
dc.sourceIJC-A Vol.60A(01) [January 2021]en_US
dc.subjectYttrium complexen_US
dc.subjectMixed functional liganden_US
dc.subjectπ-π stacking interactionsen_US
dc.subjectIntraligand charge transitionen_US
dc.titleSynthesis, crystal structure and properties of a yttrium complex based on mixed functional ligandsen_US
Appears in Collections:IJC-A Vol.60A(01) [January 2021]

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