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http://nopr.niscair.res.in/handle/123456789/55776| Title: | P2O5-mediated Friedel-Crafts acylation of activated arenes with carboxylic acid as acylating agent |
| Authors: | Kalshetti, Rupali G Mandle, Ram D Kamble, Sanjay P Sudalai, Arumugam |
| Keywords: | Friedel-Crafts acylations;Phosphorus pentoxide;Carboxylic acid;4-methoxyacetophenone |
| Issue Date: | Dec-2020 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | P2O5 has been found to be a highly efficient and environmental friendly catalyst for the liquid-phase acylation of activated aromatic substrates giving aromatic ketones (45-93%) in a regioselective manner. Both aromatic and aliphatic carboxylic acids can be employed as acylating source. The process is particularly demonstrated at 100 g scale in the case of anisole and acetic acid to produce 4-methoxyacetophenone. |
| Page(s): | 1861-1867 |
| URI: | http://nopr.niscair.res.in/handle/123456789/55776 |
| ISSN: | 0975-0983(Online); 0376-4699(Print) |
| Appears in Collections: | IJC-B Vol.59B(12) December 2020] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCB 59B(12) 1861-1867.pdf | Main Article | 229.89 kB | Adobe PDF | View/Open |
| IJCB 59B(12) 1861-1867_Suppl Data.pdf | Supplementary Data | 428.36 kB | Adobe PDF | View/Open |
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