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Title: Synthetic approach to oxa-triquinanes via olefin metathesis as a key step
Authors: Kotha, Sambasivarao
Pulletikurti, Sunil
Keywords: Oxacycles;Allylation;Olefin metathesis;Reduction;NOE
Issue Date: Dec-2020
Publisher: NISCAIR-CSIR, India
Abstract: Earlier, a simple synthetic approach to cis, syn, cis-triquinanes and propellanes from exo-nadic anhydride through metathesis approach had been demonstrated. In the present work is discussed a distinct course of observations when this methodology has been extended to oxygenated exo-nadic anhydride derivatives and the importance of stereochemistry and the role of hetero atom in the outcome of olefin metathesis has been demonstrated.
Page(s): 1868-1874
ISSN: 0975-0983(Online); 0376-4699(Print)
Appears in Collections:IJC-B Vol.59B(12) December 2020]

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