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dc.contributor.authorSrinivasan, Bikshandarkoil R-
dc.contributor.authorDhuri, Sunder N-
dc.contributor.authorNarvekar, Kedar U-
dc.identifier.issn0975-0975(Online); 0376-4710(Print)-
dc.description.abstractThe present study provides new insight into the structure of potassium hydrogen phthalate 1. The single crystal X-ray structure of 1 consists of a crystallographically independent potassium cation and a unique hydrogen phthalate anion. The µ4-heptadentate binding mode of the unique hydrogen phthalate ligand organizes the K+ ions into a layer resulting in a two-dimensional (2D) coordination polymer. As a result parallel chains of face-sharing {KO7} polyhedra extending along c are formed. The parallel chains are flanked on either side by hydrogen phthalate wings and are interlinked by vertex sharing of three polyhedra to extend the connectivity along a axis. The structure of 1 is stabilised by π∙∙∙π stacking interactions. A comparative study of the structures of alkali metal hydrogen phthalates is described.en_US
dc.publisherNISCAIR-CSIR, Indiaen_US
dc.rights CC Attribution-Noncommercial-No Derivative Works 2.5 Indiaen_US
dc.sourceIJC-A Vol.59A(12) [December 2020]en_US
dc.subjectPotassium hydrogen phthalateen_US
dc.subjectX-ray structureen_US
dc.subjectµ4-Heptadentate bindingen_US
dc.subjectCoordination polymeren_US
dc.titleCrystal structure of potassium hydrogen phthalate revisiteden_US
Appears in Collections:IJC-A Vol.59A(12) [December 2020]

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