Please use this identifier to cite or link to this item:
Title: Microwave assisted, BF3.OEt2 catalyzed efficient synthesis of tosylhydrazones and SC-XRD study of two of the synthesized tosylhydrazones
Authors: Bhuyan, Pubanita
Bhuyan, Amar Jyoti
Dutta, Bidyut Jyoti
Bharali, Sourav Jyoti
Saikia, Lakhinath
Keywords: Tosylhydrazones;Microwave assisted reaction;BF3.OEt2;Carbonyl compounds;Tosylhydrazine
Issue Date: Oct-2020
Publisher: NISCAIR-CSIR, India
Abstract: A highly efficient methodology for transformation of carbonyl compounds to their corresponding tosylhydrazones under microwave irradiation in presence of BF3.OEt2 catalyst has been developed and described here. The methodology is highly prospective for tosylhydrazone synthesis especially of diaryl ketones, as already existing procedures are found to be less effective for the same. Seventeen carbonyl compounds have been studied and found to deliver their corresponding products in excellent yield (92-98%). The products crystallize out from the reaction mixture during cooling at room temperature which excludes further purification processes. Single crystal X-ray diffraction (SC-XRD) analysis of two of the synthesized tosylhydrazones have been carried out and reported here.
Page(s): 1579-1585
ISSN: 0975-0983(Online); 0376-4699(Print)
Appears in Collections:IJC-B Vol.59B(10) [October 2020]

Files in This Item:
File Description SizeFormat 
IJCB 59B(10) 1579-1585.pdfMain Article324.28 kBAdobe PDFView/Open
IJCB 59B(10) 1579-1585_Suppl Data.pdfSupplementary Data1.34 MBAdobe PDFView/Open

Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.