Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/55456
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dc.contributor.authorDroliya, P-
dc.contributor.authorChand, D-
dc.contributor.authorNain, A K-
dc.date.accessioned2020-10-12T08:17:59Z-
dc.date.available2020-10-12T08:17:59Z-
dc.date.issued2020-10-
dc.identifier.issn0975-0975(Online); 0376-4710(Print)-
dc.identifier.urihttp://nopr.niscair.res.in/handle/123456789/55456-
dc.description1457-1469en_US
dc.description.abstractThe viscosities, η and refractive indices, nD of pure acetonitrile, methyl methacrylate, ethyl methacrylate, n-butyl methacrylate and of their binary mixtures with acetonitrile as the common component, covering the entire composition range has been measured at temperatures (298.15, 303.15, 308.15, 313.15 and 318.15) K and atmospheric pressure. Using these experimental data, the deviations in viscosity ∆η, deviations in refractive index, ∆nD, deviations in molar refraction, ∆RMhave been calculated. These excess properties are correlated by the Redlich-Kister polynomial equation. The variations of ∆η, ∆nD, ∆RM and with composition and temperature has been discussed in terms of intermolecular interactions existing in these mixtures. Further, the viscosities and refractive indices of these binary mixtures have been calculated theoretically by using various empirical and semi-empirical relations and the results are compared with the experimental findings.en_US
dc.language.isoen_USen_US
dc.publisherNISCAIR-CSIR, Indiaen_US
dc.rights CC Attribution-Noncommercial-No Derivative Works 2.5 Indiaen_US
dc.sourceIJC-A Vol.59A(10) [October 2020]en_US
dc.subjectAcetonitrileen_US
dc.subjectAlkyl methacrylatesen_US
dc.subjectExcess propertiesen_US
dc.subjectIntermolecular interactionsen_US
dc.subjectRefractive indexen_US
dc.subjectViscosityen_US
dc.titleExperimental and theoretical studies of transport and optical properties of binary mixtures of acetonitrile with some alkyl methacrylates at temperatures from 298.15 to 318.15 Ken_US
dc.typeArticleen_US
Appears in Collections:IJC-A Vol.59A(10) [October 2020]

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