Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/55454
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dc.contributor.authorGogoi, Pinky-
dc.contributor.authorBoruah, Kabita-
dc.contributor.authorBorah, Ruli-
dc.date.accessioned2020-10-12T08:06:48Z-
dc.date.available2020-10-12T08:06:48Z-
dc.date.issued2020-10-
dc.identifier.issn0975-0975(Online); 0376-4710(Print)-
dc.identifier.urihttp://nopr.niscair.res.in/handle/123456789/55454-
dc.description1476-1483en_US
dc.description.abstractFour ionic salts of N, N-disulfodiisopropylammonium cation with complex anionic speciation of metal chlorides such as [FeCl4]-, [NiCl4]2-, [Zn2Cl6]2-/[Zn4Cl10]2-, [CoCl4]2-/[CoCl3]- have been synthesized and characterized with FTIR, NMR, TGA, Raman and electronic spectra. Comparative Brønsted and Lewis acidic strength of the salts have been assessed for catalytic uses in organic reactions via UV-visible Hammett plot and FTIR spectra using pyridine as probe molecule. Band gap values obtained from Tauc plot present their semiconductor behavior to design ionic liquid-based photo catalysts in future.en_US
dc.language.isoen_USen_US
dc.publisherNISCAIR-CSIR, Indiaen_US
dc.rights CC Attribution-Noncommercial-No Derivative Works 2.5 Indiaen_US
dc.sourceIJC-A Vol.59A(10) [October 2020]en_US
dc.subjectBrønsted-Lewis acidicen_US
dc.subjectChlorometallatesen_US
dc.subjectAnionic speciationen_US
dc.subjectTransition metal cationen_US
dc.subjectAmmonium cationen_US
dc.titleStudies on coordination environment of transition metal chloride anionic speciation of N, N-disulfodiisopropylammonium ionic salts and assessment of their Brønsted-Lewis acidic propertiesen_US
dc.typeArticleen_US
Appears in Collections:IJC-A Vol.59A(10) [October 2020]

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