Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/55445
Title: N,N-Dichlorobenzyl amine: An effective decontaminant for highly toxic chemical warfare agents sulfur mustard and VX
Authors: Gutch, Pranav K
Mazumder, Avik
Gupta, Arvind K
Keywords: Sulfur mustard;VX;N,N-dichlorobenzylamine;Decontamination;NMR;GC-MS;Chemical warfare agents
Issue Date: Sep-2020
Publisher: NISCAIR-CSIR, India
Abstract: The chemical decontamination of vesicant, bis(2-chloroethyl)sulfide (Sulfur Mustard, SM) and nerve agent O-ethyl S-2-(N,N-diisopropylaminoethyl) methylphosphonothiolate (VX) has been achieved by an operationally simple method by using a new positive chlorine bearing reagent N,N-dichlorobenzylamine. Deactivation of these highly toxic chemical warfare agents has been achieved in acetonitrile-water medium. Before attempting the reactions on these highly toxic real agents, the reagent has been successfully tested for its decontaminating efficiency on the non-toxic simulants (2-chloroethyl phenyl sulfide, a simulant of Sulfur Mustard and O,S-diethyl methylphosphonothioate, simulant of VX). Progress of the decontamination reactions have been monitored by gas chromatography coupled with a flame photometric detector working in sulfur detection mode (GC-FPD(S)), 1H and 31P{1H} NMR spectroscopy. The products obtained after decontamination of Sulfur Mustard (SM) and VX have been thereafter identified by GC-MS technique. This reagent has been found to be highly advantageous over earlier reported decontaminating reagents in terms of - ease of preparation, cost effectiveness, stability, good shelf life and instantaneous conversion of both SM and VX into nontoxic products at room temperature.
Page(s): 1400-1408
URI: http://nopr.niscair.res.in/handle/123456789/55445
ISSN: 0975-0983(Online); 0376-4699(Print)
Appears in Collections:IJC-B Vol.59B(09) [September 2020]

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