Please use this identifier to cite or link to this item:
Title: Stereoselective synthesis towards (+)-trans-kumausyne employing vinylogous Mukaiyama type reaction on an α-chloro sulfide
Authors: Chowhan, L Raju
Raghavan, Sadagopan
Keywords: α-Chloro sulfide;Mukaiyama type reaction;Oxa-Michael addition;(+)-trans-Kumausyne;2-trimethylsiloxy furan
Issue Date: Aug-2020
Publisher: NISCAIR-CSIR, India
Abstract: A stereoselective synthesis towards (+)-trans-kumausyne is disclosed. The key steps of the synthesis include stereoselective C-C formation employing vinylogous Mukaiyama type reaction of an α-chloro sulfide with 2-trimethylsiloxy furan and base-catalyzed isomerization followed by intramolecular oxa-Michael reaction.
Page(s): 1199-1205
ISSN: 0975-0983(Online); 0376-4699(Print)
Appears in Collections:IJC-B Vol.59B(08) [August 2020]

Files in This Item:
File Description SizeFormat 
IJCB 59B(8) 1199-1205.pdfMain Article206.12 kBAdobe PDFView/Open
IJCB 59B(8) 1199-1205_Suppl Data.pdfSupplementary Data1.02 MBAdobe PDFView/Open

Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.