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|Title:||Synthesis and crystal structure of square-planar and mixed ligand octahedral nickel(II) O,O'-dicyclopentyl dithiophosphate complexes|
|Series/Report no.:||Int. Cl. ⁸ C07F15/04|
|Abstract:||Ammonium O,O'-dicyclopentylphosphorodithioate (dcpdtp) has been synthesized from phosphorus pentasulphide and cyclopentanol in the presence of ammonia gas. Its complexes, I=[Ni(dcpdtp)₂] and II= [Ni(bp)₂(dcpdtp)2] (bp=4-benzylpiperidine), have been synthesized and their structures characterized by using UV-vis, IR spectroscopy, magnetic susceptibility measurements and X-ray single crystal structural analysis. The complexes crystallize in the triclinic system (space groups P ī) and exhibit a slightly distorted square planar [NiS₄] and trans-octahedral [NiS₄N₂] geometry for the complexes I and II, respectively.|
|Appears in Collections:||IJC-A Vol.47A(01) [January 2008]|
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