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IJC-A Vol.47A [2008] >
IJC-A Vol.47A(01) [January 2008] >
| Title: | Synthesis, structure and properties of [Pr(DMSO)₅(H₂O)₂](μ-CN) [Co(CN)₅]•H₂O |
| Authors: | Chen, Wen-Tong
Zeng, Xi-Rui
Xu, Ya-Ping
Luo, Qiu-Yan
Chen, Hua-Long |
| Issue Date: | Jan-2008 |
| Publisher: | CSIR |
| IPC Code: | Int. Cl. ⁸ C07F5/00; C07F15/06 |
| Abstract: | A new cyano-bridged praseodymiumIII-cobaltIII complex [Pr(DMSO)₅ (H₂O)₂](μ-CN)[Co(CN)₅]•H₂O, (1), has been syn-thesized via solution reaction and characterized by X-ray diffraction. The slightly distorted square-antiprism eightfold-coordinated Pr(III) and the approximately oriented octahedrally sixfold-coordinated Co(III) are linked by a cyano-bridge group to form a dinuclear complex. The [Pr(DMSO)₅(H₂O)₂](μ-CN)[Co(CN)₅] species are held together via hydrogen bonds to form a two-dimensional slab. The magnetic properties show that complex 1 exhibits antiferromagnetic interactions. IR and thermogravimetry-differential thermal analyses (TG-DTA) are also presented. |
| Page(s): | 32-36 |
| ISSN: | 0376-4710 |
| Source: | IJC-A Vol.47A(01) [January 2008]
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