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Title: Synthesis and Electrochemical Analysis of Biologically Active Novel NiIIHMTAA and CuIIHMTAA Complexes
Authors: Vashistha, V K
Kumar, Y
Kumar, A
Das, D K
Keywords: Template method;Macrocycles;Spectral studies;Cyclic voltammetry;Antibacterial activity
Issue Date: Nov-2019
Publisher: NISCAIR-CSIR, India
Abstract: NiIIHMTAA-14 and CuIIHMTAA-14 (HMTAA-14 = dichloro[2,4,9,13,15,20-hexamethyldibenzo-1,4,8,11-tetraazacyclotetradecatetraene]) macrocyclic complexes have been synthesized by template method and characterized by multiple characterization techniques. Electrochemical studies of NiIIHMTAA-14 and CuIIHMTAA-14 macrocyclic complexes carried out on Pt disc (tip-06.1204.120.) electrode (2 mm diameter) in methanol, DMSO and acetonitrile by employing cyclic voltammetry revealing that these macrocycles undergo one-electron electrochemical processes to form stable Ni(HMTAA)0 and Cu(HMTAA)+ species. Preliminary investigation of antimicrobial activities of these novel macrocyclic complexes has also been studied.
Page(s): 788-792
ISSN: 0975-1084 (Online); 0022-4456 (Print)
Appears in Collections:JSIR Vol.78(11) [November 2019]

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