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Title: | The novel N, S-substituted nitro dienes from the reactions of some mono(alkylthio)-substituted 2-nitrodienes with piperazine and thiomorpholine and a structural study |
Authors: | Ibis, Cemil Deniz, N Gulsah |
Keywords: | Thiosubstituted nitrodiene;N,S-substituted nitrodiene;Thiomorpholine;Piperazine derivatives |
Issue Date: | Apr-2007 |
Publisher: | CSIR |
IPC Code: | Int. Cl.⁸ C07D |
Abstract: | Thiosubstituted nitrodien compounds 1a-f are obtained from 2-nitropentachlorobutadiene and some alifatic thiols. Compounds 1a-f have reacted with thiomorpholine 2 and yielded 3a-f in CH₂Cl₂. The compounds 5a-f have been obtained by the reactions of 1a-f with N-(diphenylmethyl)piperazine 4 in CH₂Cl₂. 2-Nitro-3,4,4-trichloro-1-(ethylthio)- 1-[4-(1-diphenylmethyl)-piperazin-1-yl]-1,3- butadiene 5a is synthesized and its crystal structure is determined. The compound 5a crystallizes in the orthorhombic crystal system (space group P2₁2₁2₁) with the unit cell parameters a = 9.4240(2) Å, b = 14.4007(2) Å, c = 18.1891(2) Å, ⍺ β, ϒ= 90º, V = 2468.48(7) ų, Z = 4. The structure has been solved by direct methods (SIR92) and refined to the residual index R₁ = 0.078. |
Page(s): | 674-680 |
URI: | http://hdl.handle.net/123456789/510 |
ISSN: | 0376-4699 |
Appears in Collections: | IJC-B Vol.46B(04) [April 2007] |
Files in This Item:
File | Description | Size | Format | |
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IJCB 46B(4) (2007) 674-680.pdf | 302.89 kB | Adobe PDF | View/Open |
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