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|Title:||A facile and high efficient synthesis of nitriles from aldoximes and primary amides with a mixture of triphenylphosphine/2, 3-dichloro-5, 6-dicyanobenzoquinone (PPh₃/DDQ) under neutral conditions|
|IPC Code:||Int. Cl.⁸ C07C|
|Abstract:||Aldoximes are immediately converted to their corresponding nitriles with a mixture of triphenylphosphine and 2,3-dichloro-5,6-dicyanobenzoquinone in dichloromethane under neutral conditions at room temperature., Nitriles are also formed from the reaction of primary amides with this reagent in refluxing acetonitrile under neutral conditions.|
|Appears in Collections:||IJC-B Vol.46B(04) [April 2007]|
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|IJCB 46B(4) (2007) 649-652.pdf||113.12 kB||Adobe PDF||View/Open|
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