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Title: A facile and high efficient synthesis of nitriles from aldoximes and primary amides with a mixture of triphenylphosphine/2, 3-dichloro-5, 6-dicyanobenzoquinone (PPh₃/DDQ) under neutral conditions
Authors: Aghapour, Ghasem
Amirabadi, Marjan
Keywords: Triphenylphosphine;2,3-dichloro-5,6-dicyanobenzoquinone;Oximes;Primary amides;Nitriles
Issue Date: Apr-2007
Publisher: CSIR
IPC Code: Int. Cl.⁸ C07C
Abstract: Aldoximes are immediately converted to their corresponding nitriles with a mixture of triphenylphosphine and 2,3-dichloro-5,6-dicyanobenzoquinone in dichloromethane under neutral conditions at room temperature., Nitriles are also formed from the reaction of primary amides with this reagent in refluxing acetonitrile under neutral conditions.
Page(s): 649-652
ISSN: 0376-4699
Appears in Collections:IJC-B Vol.46B(04) [April 2007]

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