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http://nopr.niscair.res.in/handle/123456789/48404| Title: | Luminescent rhenium(I) complex of azo ligand based on quinoline: Synthesis, characterization and computational investigations |
| Authors: | Sinha, Debopam Parua, Sankar Prasad Rajak, Kajal Krishna |
| Keywords: | Mononuclear Re(I) complex;X-ray structure;Photoluminescence;Life time;Computational studies |
| Issue Date: | Jun-2019 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Reaction of 7-(quinolin-8-yldiazenyl)quinolin-6-ol, HL, (where H represents the dissociable proton upon complexation) based on quinoline with [Re(CO)5Cl] in toluene afforded brown colored product of composition [Re(CO)3L]. The mononuclear Re(I) complex has been characterized unequivocally. Molecular structure of the complex fac-[Re(CO)3L] has been confirmed by single-crystal X-ray diffraction. The complex exhibited excellent photoluminescence behavior in solution state. The ground and excited-state geometries and absorption properties of the Re(I), complex has been further examined by DFT and TDDFT methods. |
| Page(s): | 621-628 |
| URI: | http://nopr.niscair.res.in/handle/123456789/48404 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.58A(06) [June 2019] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 58A(6) 621-628.pdf | Main Article | 857.05 kB | Adobe PDF | View/Open |
| IJCA 58A(6) 621-628_Suppl Data.pdf | Supplementary Data | 354.97 kB | Adobe PDF | View/Open |
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