Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/4689
Title: Kinetics and mechanism of oxidation of formic and oxalic acids by bis(pyridine) silver permanganate
Authors: Banerji, Jayshree
Kotai, Laszlo
Banerji, Kalyan K
Keywords: Kinetics
Reaction mechanisms
Oxidations
Issue Date: Jun-2009
Publisher: CSIR
Series/Report no.: Int. Cl.<sup>8</sup> C07B 33/00
Abstract: Kinetics and mechanism of oxidation of formic and oxalic acids by bis(pyridine) silver permanganate in aqueous acetic acid have been studied. The main product of oxidation is carbon dioxide. The reaction is first order each with respect to the permanganate and the reductant. The reaction is catalyzed by hydrogen ions. The oxidation of a‑deuterioformic acid exhibits a substantial primary kinetic isotope effect (<i style="">k</i><sub>H</sub>/<i style="">k</i><sub>D</sub> = 3.69 at 298 K). Suitable mechanisms have been proposed.
Description: 797-800
URI: http://hdl.handle.net/123456789/4689
ISSN: O975-0975 (Online); 0376-4710 (Print)
Appears in Collections:IJC-A Vol.48A(06) [June 2009]

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