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Title: Mono substitution in octahedral complexes: Part I-Softness constant, a new parameter for the reactivity of octahedral complexes
Authors: Sharma, S B
Tewari, I N
Gupta, P
Issue Date: Nov-1989
Publisher: NISCAIR-CSIR, India
Abstract: A new parameter, softness constant, EL, is proposed for mono substitution in octahedral complexes according to the equation,
EL = TE (MsL) - TE
where TE is the total softness value of a complex species,Mis the transition metal ion, s is the standard ligand capable of undergoing substitution reaction and L is the incoming ligand. This parameter is used to analyse the total softness values, TE,of various monosubstituted octahedral complexes (MsL) in terms of the linear approximation of equation,
TE (MsL)= ES + β’EL

where ES is a measure of the electron richness of the complex species Ms, and W is the measure of its polarisability.
Page(s): 969-972
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.28A(11) [November 1989]

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