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|Title:||Mono substitution in octahedral complexes: Part I-Softness constant, a new parameter for the reactivity of octahedral complexes|
|Authors:||Sharma, S B|
Tewari, I N
|Abstract:||A new parameter, softness constant, EL, is proposed for mono substitution in octahedral complexes according to the equation,|
EL = TE (MsL) - TE
where TE is the total softness value of a complex species,Mis the transition metal ion, s is the standard ligand capable of undergoing substitution reaction and L is the incoming ligand. This parameter is used to analyse the total softness values, TE,of various monosubstituted octahedral complexes (MsL) in terms of the linear approximation of equation,
TE (MsL)= E’S + β’EL
where E’S is a measure of the electron richness of the complex species Ms, and W is the measure of its polarisability.
|Appears in Collections:||IJC-A Vol.28A(11) [November 1989]|
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