Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/4685
Title: Synthesis and structural characterization of bis(n-propylammonium) tetrasulfidometalates
Authors: Srinivasan, Bikshandarkoil R
Naik, Ashish R
Nather, Christian
Bensch, Wolfgang
Keywords: Coordination chemistry
Crystal structure
X-ray crystallography
Tetrasulfidometalates
Molybdenum
Tungsten
Issue Date: Jun-2009
Publisher: CSIR
Series/Report no.: Int. Cl.8 C07F11/00
Abstract: The reaction of (NH4)2[MS4] (M = W, Mo) with n-propylamine (CH3-CH2-CH2-NH2) results in the formation of bis(n-propylammonium) tetrasulfidometalates (CH3-CH2-CH2-NH3)2[MS4] (M = W (1); Mo (2)). Both compounds have been characterized by elemental analysis, IR, Raman and UV-vis spectra and crystal structures. Compounds (1) and (2) are isostructural and crystallize in the centrosymmetric orthorhombic space group, Pnma. The structure consists of discrete slightly distorted tetrahedral tetrasulfidometalate [MS4]2- anions of m symmetry, separated by two crystallographically independent n-propylammonium cations located on mirror planes. The carbon atoms of the organic cations are disordered. A comparative study of twelve tetrasulfidometalates crystallizing in the orthorhombic space group Pnma is presented.
Description: 769-774
URI: http://hdl.handle.net/123456789/4685
ISSN: O975-0975 (Online); 0376-4710 (Print)
Appears in Collections:IJC-A Vol.48A(06) [June 2009]

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