NISCAIR Online Periodicals Repository

Research Journals >
Indian Journal of Chemistry -Section A (IJC-A) >
IJC-A Vol.48A [2009] >
IJC-A Vol.48A(06) [June 2009] >

Title: Synthesis and structural characterization of bis(n-propylammonium) tetrasulfidometalates
Authors: Srinivasan, Bikshandarkoil R
Naik, Ashish R
Nather, Christian
Bensch, Wolfgang
Keywords: Coordination chemistry
Crystal structure
X-ray crystallography
Issue Date: Jun-2009
Publisher: CSIR
IPC CodeInt. Cl.8 C07F11/00
Abstract: The reaction of (NH4)2[MS4] (M = W, Mo) with n-propylamine (CH3-CH2-CH2-NH2) results in the formation of bis(n-propylammonium) tetrasulfidometalates (CH3-CH2-CH2-NH3)2[MS4] (M = W (1); Mo (2)). Both compounds have been characterized by elemental analysis, IR, Raman and UV-vis spectra and crystal structures. Compounds (1) and (2) are isostructural and crystallize in the centrosymmetric orthorhombic space group, Pnma. The structure consists of discrete slightly distorted tetrahedral tetrasulfidometalate [MS4]2- anions of m symmetry, separated by two crystallographically independent n-propylammonium cations located on mirror planes. The carbon atoms of the organic cations are disordered. A comparative study of twelve tetrasulfidometalates crystallizing in the orthorhombic space group Pnma is presented.
Page(s): 769-774
ISSN: O975-0975 (Online); 0376-4710 (Print)
Source:IJC-A Vol.48A(06) [June 2009]

Files in This Item:

File Description SizeFormat
IJCA 48A(6) 769-774.pdf117.33 kBAdobe PDFView/Open
 Current Page Visits: 138 
Recommend this item


Online Submission of Articles |  NISCAIR Website |  National Knowledge Resources Consortium |  Contact us |  Feedback

Disclaimer: NISCAIR assumes no responsibility for the statements and opinions advanced by contributors. The editorial staff in its work of examining papers received for publication is helped, in an honorary capacity, by many distinguished engineers and scientists.

CC License Except where otherwise noted, the Articles on this site are licensed under Creative Commons License: CC Attribution-Noncommercial-No Derivative Works 2.5 India

Copyright © 2015 The Council of Scientific and Industrial Research, New Delhi. All rights reserved.

Powered by DSpace Copyright © 2002-2007 MIT and Hewlett-Packard | Compliant to OAI-PMH V 2.0

Home Page Total Visits: 172222 since 01-Sep-2015  Last updated on 30-Jun-2016Webmaster: