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|Title:||Synthesis & characterization of schiff base complexes of germanium derived from S-benzyldithiocarbazate|
|Authors:||Singh, S V|
Singh, R V
|Abstract:||Schiff bases derived by the condensation of S-benzyldithiocarbazate with 2-hydroxybenzaldehyde, 2-hydroxy- acetophenone, 2-hydroxy-lnaphthaldehycle, 2,4-pentanedione and 1-phenyl-l,3-butanedione react with ethyl orthogermanate in 1:2 molar ratio (metal: ligand) to form complexes of the type Ge(L)2. These ligands act as dinegatively charged tridentate species. The complexes are coloured solids, non-electrolytes and monomeric in nature. Based on electronic, infrared and proton magnetic resonance data an octahedral structure has been established for the germanium complexes.|
|Appears in Collections:||IJC-A Vol.28A(09) [September 1989]|
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