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Title: Synthesis & characterization of schiff base complexes of germanium derived from S-benzyldithiocarbazate
Authors: Singh, S V
Singh, R V
Issue Date: Sep-1989
Publisher: NISCAIR-CSIR, India
Abstract: Schiff bases derived by the condensation of S-benzyldithiocarbazate with 2-hydroxybenzaldehyde, 2-hydroxy- acetophenone, 2-hydroxy-lnaphthaldehycle, 2,4-pentanedione and 1-phenyl-l,3-butanedione react with ethyl orthogermanate in 1:2 molar ratio (metal: ligand) to form complexes of the type Ge(L)2. These ligands act as dinegatively charged tridentate species. The complexes are coloured solids, non-electrolytes and monomeric in nature. Based on electronic, infrared and proton magnetic resonance data an octahedral structure has been established for the germanium complexes.
Page(s): 804-806
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.28A(09) [September 1989]

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