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|Title:||Complexes of manganese(III) oxychlorosulphate with some nitrogen bases|
|Authors:||Zaidi, S A A|
Siddiqi, K S
|Abstract:||Manganese(III) oxychlorosulphate complexes of the type MnOSO3.Cl.L2 and MnOSO3Cl.L’ with monodentate (aniline, biphenyl amine, acetonitrile, pyridine, 3-amino-2-chloropyridine, 4-cyanopyridine, acridine) and bidentate ligands (2,2-bipyridyl and 1,10-phenanthroline) have been characterized on the basis of their elemental analysis, molar conductance, magnetic susceptibility measurements, infrared and electronic spectral data. These studies, corroborate the tridentate nature and lowering of C3v symmetry of the chlorosulphate group. The com lexes are of high-spin octahedral type as evidenced by agnetic moment values and electronic spectral bands.|
|Appears in Collections:||IJC-A Vol.28A(08) [August 1989]|
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