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Title: Synthesis, reactions, spectral and magnetic properties of bis(hexaalkoxyniobates/tantalates) of iron(II)
Authors: Shah, A
Singh, A
Mehrotra, R C
Issue Date: May-1989
Publisher: NISCAIR-CSIR, India
Abstract: Monomeric, soluble bimetallic hexaisopropoxy-niobate and -tantalate of iron(II), [Fe{M(OPri)6}2] (M = Nb, Ta), have been synthesized in quantitative yields by the reaction of anhydrous FeCl2 with K{M(OPri)6} in 1:2 molar ratio in benzene/isopropanol medium. Alcoholysis of these bimetallic isopropoxides with a variety of alcohols has been studied. All the derivatives have been characterized by elemental and group analyses, and infrared, electronic, magnetic and molecular weight data.
Page(s): 392-395
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.28A(05) [May 1989]

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