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Title: Lewis acid catalyzed amino-Claisen rearrangement: A facile one pot synthesis of 2-allylarylamines from N-allylarylamines
Authors: Jain, Seema
Pandey, Neelesh
Kishore, D
Keywords: Lewis acid catalysis;Amino-Claisen rearrangement;N-allylarylamines;2-Allylarylamines
Issue Date: Mar-2007
Publisher: CSIR
IPC Code: Int.Cl.⁸C07C
Abstract: Boron trifluoride-diethyl ether complex efficiently catalyzes a variety of amino-Claisen rearrangements of N-allylarylamines 1a-g to afford 2-allylarylamines 2a-g in moderate to good yields. N-allylarylamines having electron deficient substituents undergo rearrangement at lower temperature than electron rich ones.
Page(s): 529-531
ISSN: 0376-4699
Appears in Collections:IJC-B Vol.46B(03) [March 2007]

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