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Indian Journal of Chemistry -Section B (IJC-B) >
IJC-B Vol.46B [2007] >
IJC-B Vol.46B(03) [March 2007] >
| Title: | Lewis acid catalyzed amino-Claisen rearrangement: A facile one pot synthesis of 2-allylarylamines from N-allylarylamines |
| Authors: | Jain, Seema
Pandey, Neelesh
Kishore, D |
| Keywords: | Lewis acid catalysis
Amino-Claisen rearrangement
N-allylarylamines
2-Allylarylamines |
| Issue Date: | Mar-2007 |
| Publisher: | CSIR |
| IPC Code: | Int.Cl.⁸C07C |
| Abstract: | Boron trifluoride-diethyl ether complex efficiently catalyzes a variety of amino-Claisen rearrangements of N-allylarylamines 1a-g to afford 2-allylarylamines 2a-g in moderate to good yields. N-allylarylamines having electron deficient substituents undergo rearrangement at lower temperature than electron rich ones. |
| Page(s): | 529-531 |
| ISSN: | 0376-4699 |
| Source: | IJC-B Vol.46B(03) [March 2007]
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