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Title: New chloro, alkoxo & allied bimetallic derivatives of copper(II) & aluminium (III)
Authors: Chhipa, R C
Singh, A
Mehrotra, R C
Issue Date: May-1989
Publisher: NISCAIR-CSIR, India
Abstract: Novel chloro bimetallic alkoxides of copper(II) of the type ClCu{Al(OPi)4}(1)have been synthesized by the interaction of CuCl2 and K{Al(OPri)4}in equimolar proportions. The derivative (PriO)Cu{Al(OPri)4}) (2) has been synthesized by the reaction of CuCl2, KOPri and K{Al(OPri)4} in 1:1:1 molar ratio. The interaction of chloro bimetallic alkoxides with a number of potassium alkoxides gives mixed derivatives of the type (RO)Cu{Al(OPri)4}(3-9). The (PriO )Cu{Al(OPri)4}(2) undergoes alcohol interchange reactions, the facile nature of which is governed by the length and branching of the hydrocarbon chains of alcohols e.g. MeOH, EtOH, PrnOH, BunOH, BusOH, ButOH. The reaction with BuiOH gives only the mixed bimetallic alkoxides. The products have been characterised by elemental analyses, molecular weights, I.R, electronic spectral and magnetic susceptibility measurements.
Page(s): 396-399
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.28A(05) [May 1989]

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