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|Title:||Redox chemistry of hyponitrite: Part III-oxidation by hexacyanoferrate(III) in aqueous alkaline solution|
|Authors:||Goyal, M R|
Mittal, R K
Gupta, Y K
|Abstract:||Oxidation of hyponitrite by hexacyanoferrate(III) in alkaline solution occurs by two paths resulting in a stoichiometry of 1.21:1(oxidant:substrate). The final products are N2O,N2 and NO, and the intermediates are NO and peroxonitrite. Rate has first order dependence in [Fe(CN)] and [(N2O] and no dependence on [OH-]. The second order rate constant is found to be (0.87 ± 0.025) dm3 mol-1 at 35° and 1= 0.515 mol dm-3. Rate significantly increases in the presence of alkali metal cations.|
|Appears in Collections:||IJC-A Vol.28A(04) [April 1989]|
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