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|Title:||Ternary copper(II) complexes containing imidazole as a primary ligand & amino acids as secondary ligands|
Mohan, M Srinivas
|Abstract:||The formation constants of ternary complexes CuLA and CuL2A (where L=imidazole and A=valine, phenylalanine, tryptophan, methionine, ethionine and histidine) are reported at 35.0°C and μ = 0.2 M (KNO3). Stacking and hydrophobic interactions in these and analogous ternary complexes, are found to increase in the order: Cu-[imidazole]2A < Cu-[bis(imidazol-2-yl)methane] A < Cu-[Bipyridyl]A. The biological relevance of these model ternary complexes is discussed.|
|Appears in Collections:||IJC-A Vol.28A(04) [April 1989]|
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