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Title: Some Transition Metal Complexes of 1,2-Bis(di-p-tolylphosphino)ethane
Authors: Mercykutty, PC
Singh, Beer
Kapoor, Pramesh N
Issue Date: Apr-1989
Publisher: NISCAIR-CSIR, India
Abstract: New complexes of Ni(II), Pd(II),Pt(II) and Ru(II) with the symmetrical ditertiary phosphine, 1,2-bis(di-p-tolylphosphino)ethane (dptpe) have been synthesized and characterized by elemental analysis, 1H NMR, 31p{1H} NMR, IR and electronic spectroscopy. Complexes of the types [M(dptpe)X2 [(M= Ni, Pd or Pt; X = Cl, Br, I or NCS) and [Ru(CO)2(dptpe)X2] have been assigned cis-square planar and cis-octahedral structures, respectively, whereas the complexes [Ru(dptpe)2X2] have been assigned the trans octahedral structures.
Page(s): 328-330
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.28A(04) [April 1989]

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