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Title: Kinetics & mechanism of oxidation of dimethyl, methyl phenyl & diaryl sulphoxides by N-bromocaprolactam
Authors: Srinivasan, C
Jegatheesan, P Pandarakutty
Issue Date: Mar-1989
Publisher: NISCAIR-CSIR, India
Abstract: The oxidation of dimethyl (DMSO) and methyl phenyl (MPSON) sulphoxides by N-bromocaprolactam (NBC) follows zero order kinetics in [sulphoxide], but that of diphenyl sulphoxide (DPSO) is first order in [DPSO] HClO4 accelerates the rate of all the oxidation reactions. However, added caprolactam retards the oxidation of only DPSO.
Page(s): 250-252
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.28A(03) [March 1989]

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