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|Title:||Kinetics & mechanism of oxidation of dimethyl, methyl phenyl & diaryl sulphoxides by N-bromocaprolactam|
Jegatheesan, P Pandarakutty
|Abstract:||The oxidation of dimethyl (DMSO) and methyl phenyl (MPSON) sulphoxides by N-bromocaprolactam (NBC) follows zero order kinetics in [sulphoxide], but that of diphenyl sulphoxide (DPSO) is first order in [DPSO] HClO4 accelerates the rate of all the oxidation reactions. However, added caprolactam retards the oxidation of only DPSO.|
|Appears in Collections:||IJC-A Vol.28A(03) [March 1989]|
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