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|Title:||Rhodium(I) and ruthenium(II) complexes with monothio-β-diketones and (mono-, di-scleno)bis(β-diketone)|
Devi, M V Chandini
|Abstract:||The treatment of the rhodium carbonylated species with monothio-β-diketonesleads to the formation of monomeric complexes of general formula [Rh(CO)2(tβdk)] (H-tβdk = mono-thio- β -diketone). The carbon monoxide group can be replaced in part by triphenylphosphine, triphenylphosphite and triphenylarsine to form complexes of the type [Rh(CO) (tβdt)L] (L = PPh3, OPPh3 and AsPh3). Further, bridged binuclear rhodium(I) and ruthenium(II) complexes of (mono- and di-seleno)bis(β-diketones) have also been prepared. All the complexes obtained have been characterised by means of analytical and spectroscopic data.|
|Appears in Collections:||IJC-A Vol.29A(09) [September 1990]|
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