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Title: Rhodium(I) and ruthenium(II) complexes with monothio-β-diketones and (mono-, di-scleno)bis(β-diketone)
Authors: Jayakumar, N
Banumathi, T
Devi, M V Chandini
Natarajan, K
Issue Date: Sep-1990
Publisher: NISCAIR-CSIR, India
Abstract: The treatment of the rhodium carbonylated species with monothio-β-diketonesleads to the formation of monomeric complexes of general formula [Rh(CO)2(tβdk)] (H-tβdk = mono-thio- β -diketone). The carbon monoxide group can be replaced in part by triphenylphosphine, triphenylphosphite and triphenylarsine to form complexes of the type [Rh(CO) (tβdt)L] (L = PPh3, OPPh3 and AsPh3). Further, bridged binuclear rhodium(I) and ruthenium(II) complexes of (mono- and di-seleno)bis(β-diketones) have also been prepared. All the complexes obtained have been characterised by means of analytical and spectroscopic data.
Page(s): 885-888
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.29A(09) [September 1990]

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