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Title: Kinetics and mechanism of metal ion catalysed hydrolysis of methyl glycinate
Authors: Begum, R
Khan, A R
Pal, S C
Rahman, M L
Issue Date: Sep-1990
Publisher: NISCAIR-CSIR, India
Abstract: Hydrolysis of methyl glycinate in the presence of Cu2+, Ni2+, Co2- and Zn2+ is second order in [OH] and zero order in [ester]. The reaction rate increases with increase in [M2+]. A mechanism involving the formation of a tetracoordinated metal chelate between the metal ion and the ester has been proposed. Amongst the four metal ions studied Cu2+, seems to be the most efficient.
Page(s): 906-907
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.29A(09) [September 1990]

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