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|Title:||Kinetics and mechanism of metal ion catalysed hydrolysis of methyl glycinate|
Khan, A R
Pal, S C
Rahman, M L
|Abstract:||Hydrolysis of methyl glycinate in the presence of Cu2+, Ni2+, Co2- and Zn2+ is second order in [OH] and zero order in [ester]. The reaction rate increases with increase in [M2+]. A mechanism involving the formation of a tetracoordinated metal chelate between the metal ion and the ester has been proposed. Amongst the four metal ions studied Cu2+, seems to be the most efficient.|
|Appears in Collections:||IJC-A Vol.29A(09) [September 1990]|
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