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|Title:||Synthesis and spectral studies of some oxomolybdenum (IV) O,O'-alkylene dithiophosphates and allied complexes|
Mehrotra, R C
|Abstract:||Oxo-bis(alkylene dithiophosphato)molybdenum (IV), MoO (S2)2, (where G = - CH2CMe2CH2-, -CMe2CMe2- and -CHMeCHMe-) and oxo-bis(dialkyl dithiophosphato)molybdenum (IV), MoO[S2P(OR)2]2 (where R = Prn and Bui) have been synthesized for the first time and characterized by elemental analyses, molecular weight determinations, magnetic susceptibility measurements, IR and NMR (1H, 13C and 31P) spectral data. Based on these, a square pyramidal structure (I) incorporating bidentate dithiophosphate moieties is suggested.|
|Appears in Collections:||IJC-A Vol.29A(06) [June 1990]|
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