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Title: Kinetics and mechanism of the substitution of ethylenediaminetetraacetato-ruthenate(III) with cyanide in aqueous solution
Authors: Khan, M M Taqui
Chatterjee, Debabrata
Bajaj, H C
Bhatt, K N
Kumar, S Sanal
Issue Date: Sep-1992
Publisher: NISCAIR-CSIR, India
Abstract: The kinetics of the ligand substitution of RuIII (EDTA)(H2O)- (EDTA-ethylenediaminetetraacetate anion) with CN- has been studied spectrophotometrically as a function of ligand concentration, pH (5.0-11.0) and temperature (20-50°C). The kinetic and activation parameters are consistent with an associative interchange (Ia) mechanism.
Page(s): 714-715
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.31A(09) [September 1992]

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