Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/46052
Title: Oxygen atom transfer reactions by Ru(V) oxo complexes: Models by cytochrome P450 oxidase
Authors: Khan, M M Taqui
Chatterjee, Debabrata
Rao, A Prakash
Mehta, S H
Issue Date: Mar-1992
Publisher: NISCAIR-CSIR, India
Abstract: Ruthenium(V) oxo complexes of the composition LRuv=O {L = ethylenediaminetetraacetate (ED-TA), propylenediaminetetraacetate (PDTA), N-hydroxyethylethylenediaminetriacetate (HEOTA)} and the ion [O = RuvCl2(H2O)3]+ act as excellent catalysts in the oxygen atom transfer reactions to organic substrates. These nonporphyrinic complexes of Ru(V) oxo species are isolated and are much more stable than the Fe(V) oxo complexes of the porphyrins. They are good models for the Cyt P-450 oxidase type of reactions.
Page(s): 146-151
URI: http://nopr.niscair.res.in/handle/123456789/46052
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.31A(03) [March 1992]

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