Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/46034
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dc.contributor.authorSidhu, K S-
dc.contributor.authorSingh, Satbir-
dc.contributor.authorKumar, Anil-
dc.date.accessioned2019-03-18T09:53:12Z-
dc.date.available2019-03-18T09:53:12Z-
dc.date.issued1992-02-
dc.identifier.issn0975-0975(Online); 0376-4710(Print)-
dc.identifier.urihttp://nopr.niscair.res.in/handle/123456789/46034-
dc.description83-85en_US
dc.description.abstractAddition of triethylamine (TEA) to thionine (Th+) solutions in CH3CN /H2O (9:1, v/v) and CH3OH/H2O (9:1, v/v) solvents leads to shift in absorption maxima from 597 nm to 500 nm and from 600 nm to 515 nm respectively. The spectral changes with various TEA concentrations have isosbestic points at 533 nm and 544 nm. Various types of interactions have been analysed to show that the charge transfer initiated redox disproportionation of the dye does not explain the observed data and the interaction in fact involves 1: 1 complexation of the lewis acid/base type with K = 2.60 X 102 mol-1dm3 in CH3CN/H2O and 0.33 x 102 mol-1dm3 in CH3OH/H2O solvent.en_US
dc.language.isoen_USen_US
dc.publisherNISCAIR-CSIR, Indiaen_US
dc.rights CC Attribution-Noncommercial-No Derivative Works 2.5 Indiaen_US
dc.sourceIJC-A Vol.31A(02) [February 1992]en_US
dc.titleThionine-triethylamine interactions in mixed solventsen_US
dc.typeArticleen_US
Appears in Collections:IJC-A Vol.31A(02) [February 1992]

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