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Title: Kinetics and mechanism of oxidation of thiocyanate ion with peroxomonophosphoric acid
Authors: Mishra, Dilip Kumar
Dhas, T Peter Amala
Bhatnagar, Pankaj
Gupta, Y K
Issue Date: Feb-1992
Publisher: NISCAIR-CSIR, India
Abstract: Thiocyanate and peroxomonophosphoric acid (pmpa) react to give H3PO4 and HCN in the pH range 3,67 to 10,6, Kinetics of the reaction has been studied in acid perchlorate, acetate, phosphate and borate buffer media. The different rate laws have been deduced and suitable mechanism proposed.
Page(s): 91-96
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.31A(02) [February 1992]

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