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|Title:||Reversible binding of carbon monoxide with Ru(III) aminopolycarboxylic acid complexes|
|Authors:||Khan, M M Taqui|
Khan, N H
Kureshy, R I
|Abstract:||The reversible binding of carbon monoxide to the complexes [RuIII(EDTA-H)(H2O)] 1 and [RUIII(PDTA-H)(H2O)] 2 have been studied in aqueous solution at pH = 5 by spectrophotometric and electrochemical studies. The equilibrium constant for carbonylation, KCO was evaluated at 10°, 25° and 40°C. The thermodynamic parameters, DHᵒ, DGᵒ and DSᵒ for the carbonylation of the complexes 1 and 2 have been evaluated. The complex [Ru(PDTA-H)(CO)] 4 is more stable than the complex [Ru(EDTA-H)(CO)] 3 in solution.|
|Appears in Collections:||IJC-A Vol.31A(11) [November 1992]|
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