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|Title:||Tetraoxomolybdato and tetraoxotungstato complexes of iron(II) diimines|
Nagaraja, K S
Udupa, M R
|Abstract:||The interaction of tetraoxomolybdate or tetraoxo ngstate with iron(II) diimines gives compounds of the type(LFeO2MO2) (L = 2,2'-bipy, 1, 10-phen; M = Mo or W. The magnetic studies suggest the presence of high spin iron (II) in the complexes. The IR spectral studies indicate the bonding of diimine to iron(II) and the bidentate nature of MO42- group ligated to iron(II). Thermal decomposition behaviour of the complexes is reported. Iron(II) and molybdenum(VI) or tungsten(VI) are bridged by dioxo groups completing tetrahedral geometry.|
|Appears in Collections:||IJC-A Vol.31A(11) [November 1992]|
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