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Title: Facile enantiospecific syntheses of oxabicyclo[4.4.0]decene-diones from carvone via mild Lewis acid mediated lactonizations
Authors: Srikrishna, Adusumilli
Satyanarayana, Gedu
Keywords: (R)-Carvone;Enantiospecific;Lewis acid;Bicyclic lactones;Lactonization
Issue Date: Mar-2019
Publisher: NISCAIR-CSIR, India
Abstract: An efficient and concise enantiospecific syntheses of oxabicyclo[4.4.0]decene-diones have been accomplished starting from carvone. This strategy is a chiron based approach by making use of mild Lewis acid mediated intramolecular lactonization as key step for the formation of fused bicyclic lactones. Notably, these bicyclic lactones constitute bicyclic carbon framework of diterpene natural products.
Page(s): 362-370
ISSN: 0975-0983(Online); 0376-4699(Print)
Appears in Collections:IJC-B Vol.58B(03) [March 2019]

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