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Title: Solvent free Stobbe condensation: A green approach
Authors: Banerjee, Shubhra
Tayde, Ravibabu A
Sharma, Bhagyashree D
Keywords: Stobbe reaction;solvent-free method;classical method
Issue Date: Jun-2009
Publisher: CSIR
Abstract:  Solvent free Stobbe-condensation of methyl benzoyl propionate 1c and methyl -naphthoyl propionate 1d with benzaldehyde, anisaldehyde and furfural using dry solid potassium tertiary butoxide at room temperature and at 80°C gives arylidene benzoyl propionic acid 2a-c and arylidene naphthoyl propionic acid 2d-f respectively. Base-catalysed solvent free Stobbe condensation of dimethyl succinate 1e and aliphatic and aromatic ketones at room temperature gives 1,1-alkylidene monomethyl succinate 3a,b and 1,1-arylidene monomethyl succinate 3c respectively.
Page(s): 882-885
ISSN: 0376-4699
Appears in Collections:IJC-B Vol.48B(06) [June 2009]

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