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Title: Stereoselective epoxidation of aziridin-2-acrylaldehydes and azirinols synthesized from epoxyaldehydes catalyzed by NHC catalyst
Authors: Jin, Zhunian
Keywords: Aziridine-epoxyaldehydes;Stereoselective epoxidation;Azirinols;Ring opening reaction;NHC catalyst
Issue Date: Nov-2018
Publisher: NISCAIR-CSIR, India
Abstract: Chiral aziridine-epoxyaldehydes (d.r. up to 99:1) have been obtained from stereoselective epoxidation of aziridin-2-acrylaldehyde in the presence of proline-derivatived catalyst. The desired aziridine-epoxyaldehydes can give valuable azirinols via ring opening reaction catalyzed by NHC catalyst. These azirinol derivatives are good candidates for the synthesis of more functionalized structures.
Page(s): 1409-1415
ISSN: 0975-0983(Online); 0376-4699(Print)
Appears in Collections:IJC-B Vol.57B(11) [November 2018]

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