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|Title:||Stereoselective epoxidation of aziridin-2-acrylaldehydes and azirinols synthesized from epoxyaldehydes catalyzed by NHC catalyst|
|Keywords:||Aziridine-epoxyaldehydes;Stereoselective epoxidation;Azirinols;Ring opening reaction;NHC catalyst|
|Abstract:||Chiral aziridine-epoxyaldehydes (d.r. up to 99:1) have been obtained from stereoselective epoxidation of aziridin-2-acrylaldehyde in the presence of proline-derivatived catalyst. The desired aziridine-epoxyaldehydes can give valuable azirinols via ring opening reaction catalyzed by NHC catalyst. These azirinol derivatives are good candidates for the synthesis of more functionalized structures.|
|Appears in Collections:||IJC-B Vol.57B(11) [November 2018]|
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